ID Card:
Full name:
tRNA-dihydrouridine(47) synthase [NAD(P)(+)]
GI:
547573
Orf:
YLR401C
UniProt:
Q06053
Alpha Fold Predicted Structure:
AF-Q06053-F1
Enzyme type:
dihydrouridine synthase
Position of modification - modification:
t :47 - D
Protein sequence:
MEQNAEKRSIVGDDNSTVKRQDTSPSKGIAHIKPEYIVPLKQNENQKVAIYDEEMSSDRMTNEFAGGTNKKNKNGRGKKRGQNKNRDNRQVKEQNVLCPRLIHGDISKCSFGDNCRFVHDINLYLSTKKPEVESNIFPSCPVFNSLGFCPMGFKCRFLSSHLNKEDNILISKKEIDPDAQTIWSVKGEVNHISPERKLDLIKRRFPFTKSNEILEIIDSFQQECRDSMKPEEEVESTPQLKKQDPDVEQPVAPQVEQRNKELSEHRMKQREVYLKYKDTRYFAQEKKPLDLYHKKIVSPLTTVGNLPYRRLMRKLGADVTYSEMALAVPLIQGTNSEWALPKAHTSEFPGFGVQVACSKAWQAAKAAEALANSVSEISEINLNSGCPIDLLYRQGSGSALLDNPARMIRCLNAMNYVSKDIPITVKIRTGTKEGHPIAEGLVKRLVNETDVAAITLHGRSRQQRYTKSADWDYVSQVADTLRSAEADFIETEQGKEGRDSKNRIQFVGNGDVNNFEDWYRYLNGNENIDSVMVARGALIKPWIFEEVESQQYLDKTSTERLDILRDYAQFSMEHWGTDEYGISQCRRFFCEFMSFFHRYVPWVFVKDTL
Comments:
Dihydrouridine synthases are a conserved enzyme family that is encoded by the orthologous COG0042 gene family (Kasprzak et al. 2012 ). Dihydrouridine (D) is a post-trascriptionally modified pyrimidine nucleoside. D results from the reduction of C5,6-double bondof a uridine residue in RNA transcripts (Kasprzak et al. 2012 ) that brings to the addition of two hydrogen atoms C6 and C5. With the absence of the double bond, dihydrouridine is believed to decrease region stability, promoting dynamic motion and accommodating loop structure.Indeed, Dihydrouridine (D) appears as important in the maintenance of tRNA stability
(Alexandrov et al. 2006 ). It appears acting as a quality control marker, with its absence provoking rapid tRNA decays. D is generated post-transcriptionally by Dus enzymes and it is found in different positions of tRNAs. Dus3 modifies U47 in different tRNA substrates.
Dus3 catalyzes the D formation of tRNA through reduction of uracil base with flavin mononucleotide (FMN) as a cofactor. Not essential enzyme. Dus3 modifies all tRNAs with U at position 47, with the exception of tRNAPhe1, Phe2, and Lys1.
Reaction
Substrate
SubstrateType
Position
(Anti)Codon
Modified (Anti)Codon
Amino Acid Change
Transcript Name
Transcript Region
Cellular Localization
References
U:D
tRNA
47
IGC
IGC
tRNAAla IGC
V-loop
cytosol
U:D
tRNA
47
ICG
ICG
tRNAArg ICG
V-loop
cytosol
U:D
tRNA
47
ICU
ICU
tRNAArg ICU
V-loop
cytosol
U:D
tRNA
47
GUU
GUU
tRNAAsn GUU
V-loop
cytosol
U:D
tRNA
47
GCA
GCA
tRNACys GCA
V-loop
cytosol
U:D
tRNA
47
IAU
IAU
tRNAIle IAU
V-loop
cytosol
U:D
tRNA
47
UAU
UAU
tRNAIle UAU
V-loop
cytosol
U:D
tRNA
47
CUU
CUU
tRNALys CUU
V-loop
cytosol
U:D
tRNA
47
CAU
CAU
tRNAMet CAU
V-loop
cytosol
U:D
tRNA
47
IGU
IGU
tRNAThr IGU
V-loop
cytosol
U:D
tRNA
47
CCA
CCA
tRNATrp CCA
V-loop
cytosol
U:D
tRNA
47
GUA
GUA
tRNATyr GUA
V-loop
cytosol
U:D
tRNA
47
UAC
UAC
tRNAThr AGT
V-loop
cytosol
U:D
tRNA
47
CAC
CAC
tRNAVal CAC
V-loop
cytosol
U:D
tRNA
47
IAC
IAC
tRNAVal IAC
V-loop
cytosol
Alpha Fold Predicted Structure:
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Protein sequence:
M
E
Q
N
A
E
K
R
S
I
V
G
D
D
N
S
T
V
K
R
Q
D
T
S
P
S
K
G
I
A
H
I
K
P
E
Y
I
V
P
L
K
Q
N
E
N
Q
K
V
A
I
Y
D
E
E
M
S
S
D
R
M
T
N
E
F
A
G
G
T
N
K
K
N
K
N
G
R
G
K
K
R
G
Q
N
K
N
R
D
N
R
Q
V
K
E
Q
N
V
L
C
P
R
L
I
H
G
D
I
S
K
C
S
F
G
D
N
C
R
F
V
H
D
I
N
L
Y
L
S
T
K
K
P
E
V
E
S
N
I
F
P
S
C
P
V
F
N
S
L
G
F
C
P
M
G
F
K
C
R
F
L
S
S
H
L
N
K
E
D
N
I
L
I
S
K
K
E
I
D
P
D
A
Q
T
I
W
S
V
K
G
E
V
N
H
I
S
P
E
R
K
L
D
L
I
K
R
R
F
P
F
T
K
S
N
E
I
L
E
I
I
D
S
F
Q
Q
E
C
R
D
S
M
K
P
E
E
E
V
E
S
T
P
Q
L
K
K
Q
D
P
D
V
E
Q
P
V
A
P
Q
V
E
Q
R
N
K
E
L
S
E
H
R
M
K
Q
R
E
V
Y
L
K
Y
K
D
T
R
Y
F
A
Q
E
K
K
P
L
D
L
Y
H
K
K
I
V
S
P
L
T
T
V
G
N
L
P
Y
R
R
L
M
R
K
L
G
A
D
V
T
Y
S
E
M
A
L
A
V
P
L
I
Q
G
T
N
S
E
W
A
L
P
K
A
H
T
S
E
F
P
G
F
G
V
Q
V
A
C
S
K
A
W
Q
A
A
K
A
A
E
A
L
A
N
S
V
S
E
I
S
E
I
N
L
N
S
G
C
P
I
D
L
L
Y
R
Q
G
S
G
S
A
L
L
D
N
P
A
R
M
I
R
C
L
N
A
M
N
Y
V
S
K
D
I
P
I
T
V
K
I
R
T
G
T
K
E
G
H
P
I
A
E
G
L
V
K
R
L
V
N
E
T
D
V
A
A
I
T
L
H
G
R
S
R
Q
Q
R
Y
T
K
S
A
D
W
D
Y
V
S
Q
V
A
D
T
L
R
S
A
E
A
D
F
I
E
T
E
Q
G
K
E
G
R
D
S
K
N
R
I
Q
F
V
G
N
G
D
V
N
N
F
E
D
W
Y
R
Y
L
N
G
N
E
N
I
D
S
V
M
V
A
R
G
A
L
I
K
P
W
I
F
E
E
V
E
S
Q
Q
Y
L
D
K
T
S
T
E
R
L
D
I
L
R
D
Y
A
Q
F
S
M
E
H
W
G
T
D
E
Y
G
I
S
Q
C
R
R
F
F
C
E
F
M
S
F
F
H
R
Y
V
P
W
V
F
V
K
D
T
L
Secondary Structure Alphabet
G: 3-turn helix (310 helix)
H: α-helix
I: 𝝅-helix (5 - turn helix)
T: Hydrogen Bonded Turn
B: β-sheet
S: Bend
C: Coil (residues not present in any of the above conformations)
N: Not assigned
Download PDB Structures & DSSP Secondary Structures:
Publications:
Title
Authors
Journal
Details
PubMed Id
DOI
The specificities of four yeast dihydrouridine synthases for cytoplasmic tRNAs.
Xing F, Hiley SL, Hughes TR, Phizicky EM
J Biol Chem
[details]
14970222
-
A conserved family of Saccharomyces cerevisiae synthases effects dihydrouridine modification of tRNA.
Xing F, Martzen MR, Phizicky EM
RNA
[details]
12003496
-
Molecular evolution of dihydrouridine synthases.
Kasprzak JM, Czerwoniec A, Bujnicki JM...
BMC Bioinformatics
[details]
22741570
-
Links: